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Table of contents
- Sigma bond metathesis reaction in 2021
- Metathesis reaction lab
- Types of metathesis reactions
- Sigma bond metathesis vs oxidative addition
- Organometallic hypertextbook
- Metathesis reactions examples
- Functionalization reactions
- Organometallic reactions
Sigma bond metathesis reaction in 2021
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Metathesis reaction lab
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Types of metathesis reactions
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Sigma bond metathesis vs oxidative addition
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Organometallic hypertextbook
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Metathesis reactions examples
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Functionalization reactions
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Organometallic reactions
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Why are sigma bonds important to carbon nanotubes?
The sigma bonds confer remarkable mechanical properties to the carbon nanotubes, at least for tensile stress. Single-wall nanotubes are, in addition, extremely flexible. It is not a surprise, then, that these nanostructures are an interesting constituent for the making of composite materials.
What are the three types of σ bond activation?
The σ-bond activation reactions promoted by transition metal complexes can be grouped in three classes: oxidative addition, also denoted as homolytic cleavage, heterolytic cleavage, and σ-bond metathesis. The first step for all them is the coordination of that bond to the transition metal, to form a L n M (η 2 -X-Y) σ-complex ( Scheme 1 ).
Why does the induction of the sigma bond occur?
The induction occurs because they promote the cleavage of the bond by themselves or because lose H 2 or HCl to generate 14-valence electrons transitory osmium (II) intermediates (OsCl 2 (PR 3) 2 or OsHX (PR 3) 2 ), which are in many cases the real active species.
Which is part of sigma bond undergoes metathesis?
In organometallic chemistry, sigma-bond metathesis is a chemical reaction wherein a metal-ligand sigma bond undergoes metathesis (exchange of parts) with the sigma bond in some reagent. The reaction is illustrated by the exchange of lutetium (III) methyl complex with a hydrocarbon (R-H):
Last Update: Oct 2021